Selective oxidation of terminal aryl and aliphatic alkenes to aldehydes catalyzed by iron(III) porphyrins with triflate as a counter anion
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摘要
[Fe(Por)CF(3)SO(3)] (Por = porphyrin dianion) can efficiently catalyze selective oxidation of terminal aryl alkenes and aliphatic alkenes to aldehydes in good to high yields under mild conditions.
关键词
epoxidation-isomerizationsubstituted epoxidesruthenium porphyrinethyl diazoacetatemolecular-oxygenmetalloporphyrinrearrangementolefinsregioselectivitycomplex
